Didn't find any threads with a lot of resources relating to the learning and use of Visual Basic.NET, so I decided to compile one myself, to help users wanting to learn or brush up on their VB.NET skills.

Official information:
Microsoft's VB.NET site

VB Express - Microsoft - Free
Visual Studio - Microsoft - $299
SharpDevelop - ic#code - Free

Learn Visual Basic - MSDN
VB.NET video tutorials - MSDN
CodeProject - Lots of helpful articles on VB.NET, and an active forum.

developerFusion - dF's VB.NET forums
VBdotNETForums.com - A whole forum dedicated to VB.NET

If you want to add something to this list, PM me with the link, and I'll add it to the post. Hope this is helpful